Interacciones de nanoestructuras sobre óxido de grafeno

Claramaría Rodríguez-González; Luis Alfredo Ayala-Fonseca; Pedro Salas Castillo

doi:10.22201/ceiich.24485691e.2023.31.69765

Claramaría Rodríguez-González Centro de Investigación y Desarrollo Tecnológico en Electroquímica https://orcid.org/0000-0002-2242-9532
Luis Alfredo Ayala-Fonseca Universidad Nacional Autónoma de México, Centro de Física Aplicada y Tecnología Avanzada https://orcid.org/0000-0003-3985-7856
Pedro Salas Castillo Universidad Nacional Autónoma de México, Centro de Física Aplicada y Tecnología Avanzada https://orcid.org/0000-0002-0040-4828

DOI: https://doi.org/10.22201/ceiich.24485691e.2023.31.69765

Palabras clave: grafeno oxidado, nanopartículas, dióxido de titanio, citotoxicidad, SERS

Resumen

En el comienzo de la historia del grafeno, el óxido de grafeno representaba únicamente un paso intermedio en la metodología para la obtención de láminas de grafeno. Sin embargo, resultados posteriores de la investigación de este material mostraron que el óxido de grafeno exhibe una estructura con defectos y grupos funcionales que le confieren propiedades únicas. Dada la versatilidad de su superficie, se han propuesto distintas vías de funcionalización que han resultado en la obtención de gran variedad de materiales híbridos. En este trabajo, presentamos la obtención y caracterización de tres materiales funcionalizados basados en láminas de óxido de grafeno decoradas con nanopartículas de plata, dióxido de titanio e hidroxiapatita. Estas nanoestructuras fueron caracterizadas mediante difracción de rayos X, espectroscopia Raman y microscopia electrónica de transmisión. De forma particular se estudió la mejora en las propiedades térmicas del grafeno oxidado-nanopartículas de plata mediante análisis termogravimétrico (TGA), la mejora de las señales Raman mediante el mecanismo químico de SERS en el material decorado con dióxido de titanio y se realizó un ensayo de viabilidad celular MTT, en el que se observó que no presentaba citotoxicidad el grafeno oxidado decorado con hidroxiapatita obtenido al usar urea para la precipitación del biocerámico.

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