Síntesis de nanocompuestos oro-grafeno para la cuantificación electroquímica de peróxido de hidrógeno y glucosa

Salvador Fernández; Edgar Cuara; Maiby Valle Orta; Uriel Alejandro Sierra Gómez

doi:10.22201/ceiich.24485691e.2023.31.69768

Salvador Fernández Centro de Investigación en Química Aplicada, Laboratorio Nacional de Materiales Grafénicos, Saltillo, Coahuila https://orcid.org/0000-0001-8858-1644
Edgar Cuara Centro de Investigación en Química Aplicada, Laboratorio Nacional de Materiales Grafénicos, Saltillo, Coahuila https://orcid.org/0000-0002-0223-3137
Maiby Valle Orta Centro de Investigación en Química Aplicada, Laboratorio Nacional de Materiales Grafénicos, Saltillo, Coahuila https://orcid.org/0000-0003-4763-3107
Uriel Alejandro Sierra Gómez Centro de Investigación en Química Aplicada, Laboratorio Nacional de Materiales Grafénicos, Saltillo, Coahuila https://orcid.org/0000-0003-3440-7119

DOI: https://doi.org/10.22201/ceiich.24485691e.2023.31.69768

Palabras clave: Nanopartículas de oro, grafeno, sensor, peróxido de hidrógeno, glucosa

Resumen

La cuantificación electroquímica de biomarcadores en fluidos frecuentemente emplea nanopartículas metálicas como sustratos de detección. El desarrollo de materiales de cuantificación ha evolucionado en las últimas décadas con la incorporación de materiales de grafeno a los sistemas de medición, generando variantes de compuestos de grafeno-nanometales, Los materiales compuestos aprovechan la gran conductividad electrónica del grafeno y el aumento en la sensibilidad y selectividad que les confiere. El óxido de grafeno y productos reducidos de éste, se han usado tradicionalmente en la manufactura de compuestos de grafeno-nanopartículas metálicas. La tendencia se explica por la relativa facilidad de síntesis de los materiales oxidados de grafeno, sin embargo, esta facilidad tiene como inconveniente la pérdida de propiedades eléctricas de los materiales sintetizados y la posible disminución de sus características de detección. Para evitar estas restricciones, idealmente se deberían de usar como sustratos materiales de grafeno no oxidados, sin embargo, su manufactura no es sencilla. Reportamos aquí un método de preparación de nanoplaquetas de grafeno prístino y su fácil conversión a compuestos decorados con nanopartículas de oro. Describimos el uso de los compuestos como sustratos útiles para la cuantificación electroquímica de glucosa y peróxido de hidrógeno en fluidos.

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